On the issue of reducing nitrogen oxide emissions by diesel internal combustion engines
Abstract
Introduction. The article dwells on the problem of reducing emissions of nitrogen oxides contained in the exhaust gases (exhaust) of diesel internal combustion engines (ICE) of vehicles. In their operation when controlling harmful substances it is necessary to take into account the local impact of emissions on settlements located near highways. It is noted that there is a problem of high pollution with nitrogen-containing emissions not only of the settlements environment through which highways pass, but of vehicles drivers as well.
The purpose of the study was to analyze the operation of the SCR-NH3 neutralization system by supplying urea to the exhaust gas of diesel ICEs, as well as the study of the supplying urea method at its injection into the cylinders of the diesel ICE during the gas exhaust cycle.
Methodology and research methods. Studies show that the most important factor is the thermal effect on the reaction process which determined the effective neutralization reaction on a diesel ICE catalyst. The main contributions to the total NOx emissions are made by rated power modes of the internal combustion engine and the maximum torque modes. The relationship between the maximum NOx concentrations at Mk.max and Ne.max on the total NOx emissions in the 13-step cycle of UN Regulation No. 49 was demonstrated.
Scientific novelty and results. The disadvantages of the SCR-NH3 neutralization method have been analyzed. In this regard, it was proposed to improve the method of feeding urea and fuel into the cylinders of a diesel engine by means of a two-channel nozzle. Additional advantages could be obtained by injecting urea into the internal combustion engine cylinders.
Practical significance. The results of calculating temperature in a diesel engine cylinder with the diesel fuel maximum and minimum cyclic supply at a crankshaft speed corresponding to the maximum torque were presented. The temperature values showed that if urea was injected into the internal combustion engine cylinder after completion of the exhaust valve opening, then the conditions for the thermolysis and hydrolysis process of urea, as well as reducing reactions, would be favorable. The method of neutralizing NOx emissions contained in the flue gases of thermal stations was analyzed, the purification process of which involved the treatment of flue gases with a solution of urea without the use of catalysts in the temperature range close to the diesel engine cylinder operation.
About the Authors
A. V. ShabanovRussian Federation
PhD (Eng), expert of Expert Department
Moscow Region 141830, Dmitrov district, pos. Avtopoligon
D. V. Kondrat’ev
Russian Federation
engineer, head of the department of vehicle ecology
Moscow Region 141830, Dmitrov district, pos. Avtopoligon
V. A. Solomin
Russian Federation
engineer, head of engine laboratory of the department of vehicle ecology
Moscow Region 141830, Dmitrov district, pos. Avtopoligon
V. K. Vanin
Russian Federation
engineer, acting head of the directorate of the internal combustion engine, Center “Power units”
Moscow 125438
References
1. Azarov V.K., Kutenev V.F., Kozlov A.V., Terenchenko A.S. [Analysis of opportunities to improve energy efficiency and environmental performance of the modern mass-production car with new energy power plants]. Trudy NAMI, 2012, no. 249, pp. 23–32. (In Russian)
2. UN Regulation No. 49. Uniform provisions concerning the measures to be taken against the emission of gaseous and particulate pollutants from compressionignition engines and positive ignition engines for use in vehicles: Revision 6. Available at: https://www.unece.org/fileadmin/DAM/trans/main/wp29/wp29regs/2018/R049r6am6e.pdf (accessed 07 August 2019).
3. Shabanov A.V., Solomin V.A., Vanin V.K. [Ecological rationing of harmful exhaust gases emitted by internal combustion engines of trucks]. Trudy NAMI, 2019, no. 2 (277), pp. 79–88. (In Russian)
4. Shabanov A.V., Solomin V.A., Shabanov A.A. [The way to improve the efficiency of the neutralization system of nitrogen oxides of diesel internal combustion engines and its efficiency]. Izvestiya MGTU MAMI, 2018, no. 4 (38), pp. 77–84. (In Russian)
5. Panchishnyy V.I. [Neutralization of nitrogen oxides in diesel exhaust]. Dvigatelestroenie, 2005, no. 2, pp. 35–42. (In Russian)
6. Demidov A.A., Nadareyshvili G.G., Titchenko A.Yu. [Monitoring ammonia concentration in systems for selective reduction of diesel nitrogen oxides]. Mekhanika mashin, mekhanizmov i materialov, 2015, no. 3 (32), pp. 42–45. (In Russian)
7. Panchishnyi V.I., Vorob’ev I.Yu. [To the issue of neutralization systems simulation of automobile diesel engines]. Trudy NAMI, 2018, no. 4 (275), pp. 23–37. (In Russian)
8. Kul’chitskiy A.R. [Study of the processes of formation and development of methods for reducing emissions of harmful substances from exhaust gases of diesel engines of off-road vehicles. Dr. eng. sci. diss.]. Vladimir, 2006. P. 337. (In Russian)
9. Solomin V.A., Shabanov A.V., Shabanov A.A., Seleznev A.A. [Reducing the content of nitrogen oxides in the exhaust gas of a gasoline engine by adjusting the composition of the air-fuel mixture and the subsequent neutralization of the combustion products in the catalytic converter]. Avtomobil’naya promyshlennost’, 2019, no. 2, pp. 7–13. (In Russian)
10. Mass P’er-Anri [A method for controlling the injection of urea into a nitrogen oxide treatment system with selective catalytic reduction]. Patent 2477374. Available at: http://www.findpatent.ru/patent/247/2477374.html (accessed 07 August 2019).
11. Kulish O.N., Kuzhevatov S.A., Rebrov A.I., Orlova M.N., Antipova N.V. [The method of purification of flue gases from nitrogen oxides]. Patent RF 2314861, 10.07.2006. (In Russian)
12. Shatrov M.G., Mal’chuk V.I., Dunin A.Yu., Ezzhev A.A. [The method of joint supply of vegetable oils and diesel fuel]. [Collection of scientific papers of the international scientific and technical conference of the AAE dedicated to the 145th anniversary of MAMI. Section 2 “Piston and gas turbine engines”]. Moscow, 2010, pp. 42–49. (In Russian)
Review
For citations:
Shabanov A.V., Kondrat’ev D.V., Solomin V.A., Vanin V.K. On the issue of reducing nitrogen oxide emissions by diesel internal combustion engines. Trudy NAMI. 2020;(1):78-86. (In Russ.)